{"product_id":"investigation-on-the-thermal-decomposition-of-cyclic-hydrocarbons-with-the-shock-tube-technique","title":"Investigation on the Thermal Decomposition of Cyclic Hydrocarbons with the Shock Tube Technique","description":"The reactions involving aromatic hydrocarbons play a crucial role in the combustion chemistry for the formation and growth of polyaromatic hydrocarbons (PAHs). In this work, the thermal decomposition of the single ring aromatics benzene, phenyl and ortho-benzyne have been investigated behind reflected shock waves by using a sensitive detection technique - Atomic Resonance Absorption Spectroscopy (ARAS). The unimolecular decomposition of ortho-benzyne was investigated behind reflected shock waves by taking 1,2-diiodobenzene as the thermal source. The initial concentration of ortho-benzyne was determined in situ with I-ARAS. Simultaneously, the progress of reaction was monitored by measuring the produced H atoms with H-ARAS. By reproducing the experimental H atom concentration time profiles, a two channel decomposition model of ortho-benzyne was developed. By investigating the thermal decomposition of phenyl and benzene, a complete detailed chemical reaction model was elaborated which is able to capture the measured H atom concentration profiles over the whole investigated parameter range. Thus, the present work may contribute to a better understanding and describing of high temperature combustion of aromates which are considered as major soot precursors.","brand":"Logos Verlag Berlin","offers":[{"title":"Paperback","offer_id":48515749282041,"sku":"9783832522742","price":50.0,"currency_code":"USD","in_stock":false}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0813\/1811\/7625\/files\/imageloader_091896aa-971d-453d-a071-52d9774f1baa.jpg?v=1781209118","url":"https:\/\/hookeandplotte.com\/products\/investigation-on-the-thermal-decomposition-of-cyclic-hydrocarbons-with-the-shock-tube-technique","provider":"Hooke and Plotte Books","version":"1.0","type":"link"}